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I would even have said that both throwing and catching should be pure, just like returning an error value/handling should be pure, but the reason for the throw/returning error itself is impure. Like if you throw and ioerror it’s only after doing the impure io call, and the rest of the error reporting/handling itself can be pure.
Usually when people say “I suck at maths”, it means that they are bad at doing manual calculus. Maths is extremely useful in programming, but it’s absolutely not the same kind of math. I don’t think that the grade you had in math at school will influence in any if you will be good or bad in programming.